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Chemical Equilibrium Chemistry Revision Short Notes CBSE Self Study Material Class 11 free pdf download

Chemical Equilibrium Chemistry Revision Short Notes CBSE Self Study Material Class 11 free pdf download

Chemical Equilibrium Chemistry Revision Short Notes CBSE Self Study Material Class 11 free pdf download

Chemical Equilibrium Revision Short Notes Self Study Material Chemistry Class 11 in PDF are available for free download in ANAND CLASSES. The best tool for CBSE students now provides Chemical Equilibrium Revision Short Notes Self Study Material Chemistry Class 11 latest chapter wise notes for quick preparation of CBSE exams and school based annual examinations. Class 11 Chemistry notes on Chapter Chemical Equilibrium class 11 Notes Chemistry are also available for download in ANAND CLASSES website.


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Class 11 Chemical Equilibrium Important Short and Long Questions with Answers

The aqueous solution of sugar does not conduct electricity. However, when sodium chloride is added to water, it conducts electricity. How will you explain this statement on the basis of ionisation and how is it affected by the concentration of sodium chloride?

Answer:

Sugar is a non-electrolyte, and when it dissolves in water, there will be no ionisation. If there are no free ions, it will not conduct electricity. In contrast, When sodium chloride is added to water, it is wholly ionised to give Na+ ions and Cl ions. Due to the presence of ions, there will be electrical conductance as ions are carriers of electric current.


BF3 does not have protons but still acts as an acid and reacts with NH3. Why is it so? What type of bond is formed between the two?

Answer:

BF3 is electron-deficient and hence acts as Lewis acid. : NHhas one lone pair, which can donate to BF3 and form a coordinate bond with NH3, i.e. (NH3: → BF3).


Conjugate acid of a weak base is always stronger. The decreasing order of basic strength of the following conjugate bases will be? OH, RO, CH3COO, CI

Answer:

Conjugate acids of given bases are H2O, ROH, CH3COOH, and HCl.

Their acidic strength is in the order.

HCl > CH3COOH > H2O >ROH.

Hence, their conjugate bases will have strength in the order.

RO > OH > CH3COO > CI


Arrange the following in increasing order of pH.

KNO(aq), CH3COONa (aq), NH4Cl (aq), C6H5COONH(aq)

Answer:

NH4Cl < C6H5COONH< KNO< CH3COONa

KNOis formed from a strong acid, nitric acid and strong base, potassium hydroxide. Salts of strong acid and strong base hydrolyse to form a neutral solution. Thus its pH will be nearly 7. Sodium acetate is formed from a weak acid, acetic acid, and strong base sodium hydroxide. Thus its pH will be more than 7.C6H5COONHis formed from a mild acid, C6H5COOH and a weak base, NH4OH. Thus its pH will be less than 7. NH4Cl is formed from a weak base, NH4OH, and strong acid, HCl. Thus its pH value would be less than 5.


The value of Kc for the reaction 2HI (g) ⇋ H2 (g) + I2 (g) is 1 x 10-4. At a given time, the composition of reaction mixture is [HI] = 2 x 10-5 mol, [I2 ] = 1 x 10-5 mol. Determine the direction in which the reaction will proceed?

Answer:

At a given time, the reaction quotient Q for the reaction will be given by the expression.

Q = [H2 ][I2 ] / [HI]

Q = 1 X 10-5 X 1 X 10-5 / (2 X 10-5 )2

Q = 1 / 4

Q = 0.25

Q = 2.5 X 10-1

As the value of the reaction quotient is greater than the value of Kc , i.e. 1×10−4, the reaction will proceed in the reverse direction.


On the basis of the equation pH = – log [H+], the pH of 10-8 mol dm-3 solution of HCI should be 8. However, it is observed to be less than 7.0. Explain the reason.

Answer:

Here, the water concentration cannot be neglected since the solution is very dilute.

[H3O+] = 10−8 +10−7 M

[H3O+] = 10−8 (1 + 10)

[H3O+] = 11 X 10−8 M

pH = – log [H3O+]

pH = – log 11 X 10−8 M

pH = 8 – log 11

pH = 8 – 1.04

pH = 6.96

pH will be less than 7.0.


The pH of a solution of a strong acid is 5.0. What will be the pH of the solution obtained after diluting the given solution 100 times?

Answer:

pH = 5 means [H+] = 10−5

On diluting 100 times ,

[H+] = 10−5 100 = 10−7

On calculating the pH using the equation pH = − log [H+], the pH value comes out to be 7, which is impossible.

Hence, Total H+ ion concentration = H+ ions from acid + H+ ion from water

[H+] = 10−7 +10−7 M

[H+] = 2 X 10−7

pH = 7 – 0.3010

pH = 6.699


The pH of 0.08 mol dm-3 HOCI solution is 2.85. Calculate its ionisation constant.

Answer:

pH of HOCl = 2.85

But, – pH = log [H+]

∴ -2.85 = log [H+]

-3.15 = log [H+] [H+] = 1.413 × 10–3

For the weak monobasic acid [H+] = (Ka X C) 1 / 2

Ka = [H+2 / C

Ka = (1.413 × 10–3 )2 / 0.08

Ka = 24.957 × 10–6

Ka = 2.4957 × 10–5


Calculate the pH of a solution formed by mixing equal volumes of two solutions A and B of a strong acid having pH = 6 and pH = 4 respectively.

Answer:

The pH of solution A = 6,

Therefore, the concentration of [H+] ion in solution A=10−6 mol / L

The pH of solution B = 4

Therefore, the concentration of [H+] ion in solution B=10−4mol / L.

On mixing one litre of each solution, total volume = 1L + 1L = 2L.

Amount of H+ ions in 1L of solution A = concentration × Volume (V) =

Amount of H+ ions in 1L of solution A = 10−6 X 1 = 10−6

Amount of H+ ions in 1L of solution B =10−4 X 1 = 10−4

∴ The total amount of H+ ions in the solution formed by mixing solutions A and B is (10−5 mol + 10−4 mol)

This amount is present in 2L solution,

∴ Total [H+] = 10−4 (1 + 1.01) / 2 mol / L

Total [H+] = 1.01 X 10−4 / 2 mol / L

Total [H+] = 0.5 X 10−4 mol / L

Total [H+] = 5 X 10−5 mol / L

pH = – log [H+]

pH = – log [5 X 10−5]

pH = – [ log 5 – 5 log 10]

pH = – log 5 + 5

pH = 5 – log 5

pH = 5 – 0.6990

pH = 4.3010

pH = 4.3

Thus, the pH will be 4.3.


The solubility product of Al(OH)3 is 2.7 x 10-11. Calculate its solubility in g / L and also find out the pH of this solution. (Atomic mass of Al = 27 u).

Answer:

Let S be the solubility of Al(OH)3

Ksp = [Al3+] [OH]3

Ksp = (S) (3S)3

Ksp = 27S4

S= Ksp / 27

S= 27 × 10-11 / 27 x 10

S= 1 x 10 -12 mol / L.

S = 1 x 10 -3 mol / L.

(i) Solubility of Al(OH)3: Molar mass of Al(OH)3 is 78g.

Therefore, the solubility of Al(OH)3 in g / L = 1×10 × 78 g / L

Solubility of Al(OH)3 in g / L = 78 × 10−3 g / L

Solubility of Al(OH)3 in g / L = 7.8 × 10−2 g / L

(ii) pH of the solution: S = 1 × 10−3 mol / L

[OH] = 3S = 3 × 1 × 10−3 = 3 × 10−3

pOH =3 − log 3

pH = 14 − pOH = 11 + log 3 = 11.4771.


A reaction between ammonia and boron trifluoride is given below:

: NH3 + BF3 → H3N: BF3

Identify the acid and base in this reaction. Which theory explains it? What is the hybridisation of B and N in the reactants?

Answer:

NH3 is Lewis base, while BF3 is Lewis acid. Lewis’s electronic theory of acids and bases explains it.

The hybridisation state of nitrogen in NH3 is sp3 hybridised, and boron in BF3 is sp2 hybridised.


Following data is given for the reaction: CaCO3(s) → CaO (s) + CO(g)

Δf H [CaO (s)] = – 635.1 kJ / mol

Δf H [CO(g)] = – 393.5 kJ / mol

Δf H [CaCO(s)] = – 1206.9 kJ / mol

Predict the effect of temperature on the equilibrium constant of the above reaction.

Answer:

Δf H = Δf H [CaO (s)] + Δf H [CO2 (g)] − Δf H [CaCO(s)]

∴ Δf H = 178.3 kJ / mol.

The reaction is endothermic.

Hence, according to Le Chatelier’s principle, the reaction will proceed in the forward direction on increasing temperature.


How can you predict the following stages of a reaction by comparing the value of Kc and Qc?

(i) Net reaction proceeds in the forward direction.

(li) Net reaction proceeds in the backward direction.

(iii) No net reaction occurs.

Answer:

The values of Kc and Qc are self-explanatory and less than or greater than one another decides the direction in which reaction will proceed as follows-

(i) As Qc < Kc, the reaction will proceed in the direction of products (forward direction).

(ii) If Qc > Kc, the reaction will proceed in the direction of reactants (reverse direction).

(iii) If Qc = Kc, no net reaction will occur.


On the basis of the Le Chatelier principle explain how temperature and pressure can be adjusted to increase the yield of ammonia in the following reaction.

N(g) + 3H2 (g) ⇋ 2NH3 (g) ΔH = – 92.38 kJ mol-1

What will be the effect of addition of argon to the above reaction mixture at constant volume?

Answer:

According to Le Chatelier’s principle, raising the temperature shifts the equilibrium to the left and decreases the equilibrium concentration of ammonia since it is an exothermic reaction. In other words, low temperature and high pressure are favourable for a high yield of ammonia. There will be no change in equilibria on the addition of argon (Ar).


A sparingly soluble salt having general formula Ax By and molar solubility S is in equilibrium with its saturated solution. Derive a relationship between the solubility and solubility product for such salt.

Answer:

Axp+ + Byq− ⇋ xAp+ (aq) + yBq− (aq)

S moles of A B dissolve to give x S moles of Ap+ and y S moles of Bq.

Ksp = [Ap+[Bq−y

Ksp =[x5] [y5] y

x+y.


Write a relation between ΔG and Q and define the meaning of each term and answer the following:

(a) Why a reaction proceeds forward when Q < K and no net reaction occurs when Q = K.

(b) Explain the effect of an increase in pressure in terms of reaction quotient O. for the reaction: CO (g) + 3H(g) ⇋ CH(g) + H2O (g)

Answer:

(a) ΔG = ΔG⊝ + RT ln Q

ΔG = Change in free energy as the reaction proceeds,

ΔG = Standard free energy change,

Q = Reaction quotient,

R = Gas constant,

T = Absolute temperature.

Since ΔG = − RTlnK

∴ ΔG = −RTlnK + RTlnQ

ΔG = RT lnQ / K

If Q < K, ΔG will be negative. The reaction will proceed in forward direction.

If Q = K, ΔG = 0, the reaction is in equilibrium, and no net reaction is there.

(b) CO (g) + 3H(g) ⇋ CH(g) + H2O (g),

According to the Le Chatiliers principle, when the pressure increases, the equilibrium will shift in that direction where there are fewer gas molecules.

As per the available information,

The number of moles of reactants = 1 + 3 = 4

The number of moles of product = 1 + 1 = 2

Hence, the equilibrium will shift forward as the number of moles of product is less.


Important Topics Covered in Class 11 Chemistry of Chapter Equilibrium are listed below:

  1. Solid-liquid Equilibrium
    • Liquid-vapour Equilibrium
    • Solid-vapour Equilibrium
    • Equilibrium Involving Dissolution of Solid or Gases in Liquids
    • General Characteristics of Equilibria Involving Physical Processes
  2. Equilibrium in Chemical Processes – Dynamic Equilibrium
  3. Law of Chemical Equilibrium and Equilibrium Constant
  4. Homogeneous Equilibria
    • Equilibrium Constant in Gaseous Systems
  5. Heterogeneous Equilibria
  6. Applications of Equilibrium Constants
    • Predicting the Extent of a Reaction
    • Predicting the Direction of the Reaction
    • Calculating Equilibrium Concentrations
  7. Relationship between Equilibrium Constant K, Reaction Quotient Q and Gibbs Energy G
  8. Factors Affecting Equilibria
    • Effect of Concentration Change
    • Effect of Pressure Change
    • Effect of Inert Gas Addition
    • Effect of Temperature Change
    • Effect of a Catalyst
  9. Ionic Equilibrium in Solution
  10. Acids, Bases and Salts
    • Arrhenius Concept of Acids and Bases
    • The Bronsted-lowry Acids and Bases
    • Lewis Acids and Bases
  11. Ionisation of Acids and Bases
    • The Ionisation Constant of Water and Its Ionic Product
    • The pH Scale
    • Ionisation Constants of Weak Acids
    • Ionisation of Weak Bases
    • The Relation Between Ka and Kb
    • Di- and Polybasic Acids and Di- and Polyacidic Bases
    • Factors Affecting Acid Strength
    • Common Ion Effect in the Ionisation of Acids and Bases
    • Hydrolysis of Salts and the Ph of Their Solutions
  12. Buffer Solutions
  13. Solubility Equilibria of Sparingly Soluble Salts
    • Solubility Product Constant
    • Common Ion Effect on Solubility of Ionic Salts

Brief Summary of Chapter Chemical Equilibrium

What is Chemical Equilibrium?

Chemical equilibrium is a state in a chemical reaction in which the concentrations of reactants and products remain constant over time. This does not mean that the forward and backward reactions have stopped, but rather that they are occurring at the same rate.

Types of Chemical Equilibrium

There are two main types of chemical equilibrium:

  • Homogeneous equilibrium: This occurs when all of the reactants and products are in the same phase, such as a gas or a solution.
  • Heterogeneous equilibrium: This occurs when the reactants and products are in different phases, such as a solid and a gas.

Characteristics of Chemical Equilibrium

Chemical equilibrium is characterized by the following:

  • The concentrations of all reactants and products remain constant over time.
  • The rate of the forward reaction is equal to the rate of the backward reaction.
  • The system is dynamic, meaning that the forward and backward reactions are still occurring, but at the same rate.
  • The system is reversible, meaning that the reaction can go in both the forward and backward directions.

Factors Affecting Chemical Equilibrium

The following factors can affect the position of equilibrium in a chemical reaction:

  • Concentration: Changes in the concentration of reactants or products can shift the equilibrium position. For example, increasing the concentration of reactants will shift the equilibrium position to the right, favoring the formation of products.
  • Temperature: Increasing the temperature of a chemical reaction will generally shift the equilibrium position to the right, favoring the formation of products that absorb heat.
  • Pressure: Changing the pressure of a chemical reaction can shift the equilibrium position in the direction that produces fewer moles of gas. For example, increasing the pressure of a reaction that produces two moles of gas from one mole of gas will shift the equilibrium position to the left, favoring the formation of reactants.
  • Catalyst: A catalyst is a substance that speeds up the rate of a chemical reaction without being consumed itself. A catalyst can shift the equilibrium position of a reaction, but it cannot change the extent to which the reaction reaches equilibrium.

Le Chatelier’s Principle

Le Chatelier’s principle states that when a stress is applied to a system at equilibrium, the system will respond in a way that tends to relieve the stress.

For example, if the concentration of a reactant is increased, the equilibrium position will shift to the right, favoring the formation of products. This is because the system is trying to relieve the stress of the increased concentration of reactants by consuming them and forming products.

Examples of Chemical Equilibrium

There are many examples of chemical equilibrium in the world around us. Here are a few:

  • The evaporation of water is in equilibrium with its condensation.
  • The dissolution of a salt in water is in equilibrium with its precipitation.
  • The dissociation of a weak acid in water is in equilibrium with its association.
  • The Haber process for the synthesis of ammonia is in equilibrium.

Importance of Chemical Equilibrium

Chemical equilibrium is an important concept in chemistry because it helps us to understand how chemical reactions work and how to control them. For example, chemical equilibrium is used in the production of many industrial chemicals and in the design of chemical reactors.


Chemical Equilibrium Revision Short Notes Self Study Material Chemistry Class 11

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Download CBSE class 11th revision notes for Chapter Chemical Equilibrium class 11 Notes Chemistry in PDF format for free. Download revision notes for Chemical Equilibrium class 11 Notes Chemistry and score high in exams. These are the Chemical Equilibrium class 11 Notes Chemistry prepared by team of expert teachers of ANAND CLASSES. The revision notes help you revise the whole chapter in minutes. Revising notes in exam days is on of the best tips recommended by teachers during exam days.


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Last-minute revision is never easy. Our CBSE of Chapter Chemical Equilibrium revision notes summarise key points of a chapter in an easy to remember form. They provide students with an additional edge and help boost confidence before appearing for their examinations. The CBSE Chemistry Revision Notes of Chapter Chemical Equilibrium have been widely compiled by teachers with close to 30 years of experience and after studying the last ten years of examination papers. Further, they are all made with the latest educational year’s subject material so that any deviation in the syllabus is considered as well. CBSE Class 11 of Chapter Chemical Equilibrium revision notes are very important and useful because, for the science and maths subjects, it is essential that all questions are explained in a quick and efficient manner. By studying from certain revision notes and using sample papers, students will no doubt be able to relieve any tension before the examinations as they will be fully prepared in advance for their board exams. Also, the CBSE Class 11 Chemistry Revision Notes of Chapter Chemical Equilibrium PDF is easy to read and includes all the material, all clearly described and in a short manner. Students can also use the sample papers that ANAND CLASSES provides for Class 11 along with the CBSE Class 11 of Chapter Chemical Equilibrium revision notes provided. Together, students will be prepared to answer every type of question, both objective and subjective and aim for the best in their last year of school.


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Frequently Asked Questions on CBSE Class 11 Chemistry Notes of Chapter Equilibrium

Chemical equilibrium relates to such a state when the reactants, as well as products, will no longer undergo any further change. In such a case, the rate of forwarding and backward reaction remains the same. The concept of equilibrium becomes important for students to grasp the advanced topics. Class 11 Chemistry chapter equilibrium notes provide a clear discussion on it.
Q1

What is equilibrium and what is an example?

The state in which the measurable properties of the system such as pressure, density, colour or concentration do not undergo any further noticeable changes with time under a given set of conditions is said to be a state of equilibrium. Example: 2HI ⇋ H2 + I2

Q2

What are KP and KC in equilibrium?

Kp is the equilibrium constant used when partial pressures of the species are given and Kc is the equilibrium constant used when equilibrium concentrations are expressed in molarity.

Q3

Why is equilibrium important in chemistry?

When the quantities of reactants and products are stable – their ratio does not change a chemical reaction is in equilibrium. This suggests that the reaction has reached a point where the reactant and product amounts remain constant over time, since the forward and backward reactions are at the same rate.

Q4

What is the pH formula?

pH is described as the negative of the logarithm of the molar hydronium-ion concentration. pH formula is -log [H3O+].

Q5

What is stated in ‘Le Chatelier’s’ principle?

It states that changes in the temperature, pressure, volume, or concentration of a system will result in predictable and opposing changes in the system in order to achieve a new equilibrium state.

Q6

What is the meaning of Lewis acid and Lewis base?

A Lewis acid is a substance that accepts a pair of electrons to form a covalent bond. A Lewis base is a substance that donates a pair of electrons to form a covalent bond.

Q7

What are electrolytes?

Electrolytes are minerals in your blood and other body fluids that carry an electric charge.


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Added to that, individual attention is given to every student at any point of time irrespective of their merit. Er Neeraj Anand on hand to the students to clear their doubts even separately, if requisite. Our regular tests help students to mark the weaknesses and get rid of them, understand the strengths and thus perform remarkably well in the JEE main  and advanced & NEET exams.

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